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Beilstein J. Org. Chem. 2013, 9, 1326–1332, doi:10.3762/bjoc.9.149
Graphical Abstract
Figure 1: ORTEP structure of trans-2a.
Scheme 1: Formation of bicyclic dihydrosilole 2a under high concentration conditions.
Scheme 2: Plausible reaction mechanism.
Scheme 3: Reaction 1a with Et3GeH.